Iodocyclohexane
Names | |
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Preferred IUPAC name Iodocyclohexane | |
Other names Cyclohexyl iodide | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.009.962 |
EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
C6H11I | |
Molar mass | 210.058 g·mol−1 |
Appearance | colorless to slightly reddish yellow liquid |
Density | 1.624 g/mL |
Boiling point | 180 °C (356 °F; 453 K) |
Insoluble | |
Hazards | |
Flash point | 71 °C (160 °F; 344 K) |
Related compounds | |
Related compounds | Chlorocyclohexane Bromocyclohexane Fluorocyclohexane |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Iodocyclohexane is an organoiodine compound with the chemical formula C6H11I.[1][2]
Synthesis
[edit]Iodocyclohexane has been prepared by the addition of hydrogen iodide to cyclohexene.[3]
Alternatively, it can be prepared by the reaction of cyclohexane and iodoform.[4]
Physical properties
[edit]Iodocyclohexane forms colorless to slightly reddish yellow liquid. It is soluble in ethanol, ether, and acetone.[1]
Uses
[edit]The compound has been used as reagent in demethylation of aryl methyl ethers in DMF under reflux condition.[1]
See also
[edit]References
[edit]- ^ a b c "B24840 Iodocyclohexane, 98%, stab. with copper". Alfa Aesar. Retrieved 21 June 2023.
- ^ "Iodocyclohexane". Sigma Aldrich. Retrieved 21 June 2023.
- ^ Stone, Herman; Shechter, Harold (1951). "Iodocyclohexane". Organic Syntheses. 31: 66. doi:10.15227/orgsyn.031.0066.
- ^ "Synthesis of iodocyclohexane from cyclohexane and iodoform" (PDF). oc-praktikum.de. Retrieved 21 June 2023.