Carbonate nitrate

From Wikipedia the free encyclopedia

Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.

Hydrotalcite can contain carbonate and nitrate ions between its layers. Magnesium can be substituted by nickel, cobalt or copper.[1]

Oxycarbonitrates containing an alkaline earth metal and cuprate and nitrate and carbonate anions in layers, form a family of superconducting materials.[2]

List[edit]

name formula ratio formula

weight

crystal

system

space

group

unit cell Å volume density comment ref
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate (Co(NH3)5(CO3))(NO3)·H2O 1:1 monoclinic P21/c a = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4 931.2 [3]
(Co(NH3)4CO3)(NO3)·(H2O)0.5 1:1 monoclinic P21/n a=7.4319 b=22.647 c=10.4103 β=92.052° Z=8 1756 1.95 violet-red; loses water at 125°C [4][5]
(Co(NH3)4(CO3)(NO3))2·H2O 1:1 monoclinic P21/n a=7.4960 b=22.673 c=10.513 β=91.41° Z=4 1786.12 1.915 [6]
[Co(NH3)5CO3]NO3·1/2H2O 1:1 monoclinic P21/m a=7.6661 b=9.6212 c=7.0725 β=106.261° Z=2 500.78 1.82 pink [7]
[Co(NH3)5CO3]NO3·H2O 1:1 monoclinic P21 a = 7.6733 b = 9.6398 c = 7.0852 β = 106.195° 1.87 pink [8]
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate (Co(CO3)(NH3)4)(NO3) 1:1 monoclinic P21/c a = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4 931.2 pink [9]
[(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O 1:2 triclinic P1 a=7.7038 b=9.672 c=10.861 α=104.826° β=109.405° γ=91.553° [10]
cis-(Carbonato-O,O')-bis(2,2'-bipyridine)-cobalt(iii) nitrate pentahydrate [Co(C10H8N2)2(CO3)]NO3·5H2O monoclinic C2/c a=10.931 b=16.039 c=14.435β=101.94° Z=4 2476 [11]
Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 3:2 1029.39 hexagonal P63/mcm a = 9.5732 c = 15.820 Z=2 1255.6 2.723 UV cut off 231 nm;

(-) uniaxial;

birefringence 0.14 @ 546 nm

[12]
Na3Rb6(CO3)3(NO3)2Br·6H2O 3:2 hexagonal P63/mcm a=9.6086 c=15.864 Z=2 [13]
N0.2C0.8Sr3Cu2O7.0 [2]
C0.8N0.2Sr2CuO5.3 [14]
N0.5C0.5Sr3Cu2O7.4 Tc=33 [2]
N0.5C0.5Sr2CaCu2O7.45 Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.5 Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.8 Tc=101 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.85 Tc=101 [2]
N0.5C0.5Sr2Ca2Cu3O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O11.8 Tc=99K [2]
N0.5C0.5Sr2Ca3Cu4O11.9 Tc=101K [2]
N0.5C0.5Sr3.4Ca1.6Cu4O12.0 Tc=105K [2]
YCaBa4Cu5(NO3)0.3(CO3)0.7O11 superconductor Tc=82k [15]
hexakis(μ4-(R)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-diaqua-pentakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate tetrahydrate monoclinic P21 a=15.6719 b=25.570 c=16.472 β=101.838° colourless [16]
hexakis(μ4-(S)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-heptakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate pentahydrate monoclinic P21 a=15.662 b=25.624 c=16.460 β=101.924° [16]
pentakis(μ3-Glycine hydroxamato)-tetraaqua-(nitrato-O)-(nitrato-O,O')-penta-copper(ii)-europium(iii) tetrahydrate [EuCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2O triclinic P1 a=11.163 b=11.524 c=13.323 α=93.85° β=94.79° γ=107.14° Z=2 1624 2.425 [17]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-gadolinium(iii) hydrate [GdCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2O triclinic P1 a=11.206 b=11.505 c=13.298 α=94.026° β=94.942° γ=107.558° Z=2 1620.2 2.440 dark blue [17]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-dysprosium(iii) hydrate [DyCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.28H2O triclinic P1 a=11.1083 b=11.4991 c=13.2894 α=93.923° β=94.771° γ=107.147° Z=2 1608.7 2.460 dark blue [17]
[HoCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.445H2O triclinic P1 a=11.2027 b=11.4955 c=13.247 α=94.001° β=94.784° γ=107.518° Z=2 1613.0 2.467 dark blue [17]
bis(μ4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II))

tetranitrate trihydrate

((Pt(NH3)2)4(CO3)2)(NO3)4·(H2O)3 2:4 triclinic P1 a=11.324 b=12.151 c=10.926 α=103.792° β=111.266° γ=75.845° blue [18]
(Tl5/6Cr1/6)Sr4Cu2(CO3)1/2(NO3)1/2O7 tetragonal a = 3.8320 c = 16.4112 [19]
[Pb6O4](OH)(NO3)(CO3) 1:1 orthorhombic Pnma a=30.557 b=5.809 c=7.183 Z=4 1274.9 [20]

References[edit]

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