Yttrium nitride
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| Identifiers | |
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3D model (JSmol) | |
| ECHA InfoCard | 100.042.939 |
| EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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| Properties | |
| YN | |
| Molar mass | 102.913 g/mol |
| Appearance | black crystalline |
| Density | 5.60 g/cm3 |
| Melting point | ~3033K (2760°C; 5000°F) |
| soluble | |
| Structure | |
| cubic, cF8 | |
| Fm3m, No. 225 | |
| Hazards | |
| GHS labelling: | |
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| Danger | |
| H228, H314 | |
| P210, P240, P241, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P405, P501 | |
| Safety data sheet (SDS) | External MSDS |
| Related compounds | |
Other anions | Yttrium phosphide Yttrium(III) arsenide Yttrium(III) antimonide |
Other cations | Scandium nitride Lutetium nitride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Yttrium nitride, YN, is a nitride of yttrium.
Yttrium nitride is hard ceramic material similar to titanium nitride and zirconium nitride.
The nitrides of lanthanum, scandium, and yttrium show semiconducting properties and additionally the lattice structure of YN differs only by 8% from that of gallium nitride. This makes YN a possible buffer layer between a substrate and the GaN layer during GaN crystal growth.
References
[edit]- CP Kempter; NH Krikorian; JC McGuire (1957). "The Crystal Structure of Yttrium Nitride". The Journal of Physical Chemistry. 61 (9): 1237–1238. doi:10.1021/j150555a023.
- Mancera, Luis; Rodr guez, Jairo A; Takeuchi, Noboru (2003-05-07). "First principles calculations of the ground state properties and structural phase transformation in YN". Journal of Physics: Condensed Matter. 15 (17): 2625–2633. Bibcode:2003JPCM...15.2625M. doi:10.1088/0953-8984/15/17/316. ISSN 0953-8984. S2CID 122683613.
- De La Cruz, W.; Díaz, J.A.; Mancera, L.; Takeuchi, N.; Soto, G. (November 2003). "Yttrium nitride thin films grown by reactive laser ablation". Journal of Physics and Chemistry of Solids. 64 (11): 2273–2279. Bibcode:2003JPCS...64.2273D. doi:10.1016/S0022-3697(03)00259-2.
- G. Soto, M.G. Moreno-Armentaa & A. Reyes-Serrato (2008). "First principles study on the formation of yttrium nitride in cubic and hexagonal phases". Computational Materials Science. 42 (1): 8–13. arXiv:cond-mat/0703568. doi:10.1016/j.commatsci.2007.06.003. S2CID 97080839.
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