Thallium(I) nitrate
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| Names | |
|---|---|
| IUPAC name thallium(I) nitrate | |
| Other names thallous nitrate | |
| Identifiers | |
3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.030.235 |
| EC Number |
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PubChem CID | |
| UNII | |
CompTox Dashboard (EPA) | |
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| Properties | |
| TlNO3 | |
| Molar mass | 266.39 g/mol |
| Appearance | colorless solid |
| Density | 5.55 g/cm3 |
| Melting point | 206 °C (403 °F; 479 K) |
| Boiling point | 430 °C (806 °F; 703 K) |
| 95 g/L (20 °C) | |
| Hazards | |
| GHS labelling: | |
    | |
| Danger | |
| H272, H300+H330, H373, H411 | |
| P210, P260, P273, P301+P310+P330, P304+P340+P310, P403+P233 | |
| NFPA 704 (fire diamond) | |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 15 mg/kg (mouse, oral) |
| Safety data sheet (SDS) | Fischer Scientific |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Thallium(I) nitrate, also known as thallous nitrate, is a thallium compound with the formula TlNO3. It is a colorless and highly toxic salt.
Preparation
[edit]Thallium(I) nitrate can be produced by reacting thallium(I) iodide with nitric acid.[1]
However, the production is simpler starting from the metal, its hydroxide or the carbonate: [2]
- TlOH + HNO3 → TlNO3 + H2O
- Tl2CO3 + 2 HNO3 → 2 TlNO3 + CO2 + H2O
Toxicity
[edit]Thallium(I) nitrate is extremely toxic, like many other thallium compounds. It is highly toxic by ingestion but can also be absorbed through skin due to its solubility in water.[3]
See also
[edit]References
[edit]- ^ R. Pribil, V. Veselý, K. Kratochvíl (1961), "Contributions to the basic problems of complexometry--IV : Determination of thallium", Talanta (in German), vol. 8, no. 1, pp. 52–54, doi:10.1016/0039-9140(61)80037-4
{{citation}}: CS1 maint: multiple names: authors list (link) - ^ Heinrich Remy: Lehrbuch der Anorganischen Chemie Band I + II, Leipzig 1973.
- ^ National Center for Biotechnology Information (2023). PubChem Compound Summary for CID 24937, Thallium nitrate. Retrieved March 20, 2023 from https://pubchem.ncbi.nlm.nih.gov/compound/Thallium-nitrate.