Cerium monosulfide
| Names | |
|---|---|
| Other names Cerium sulfide (CeS) | |
| Identifiers | |
3D model (JSmol) | |
| ChemSpider | |
CompTox Dashboard (EPA) | |
| |
| |
| Properties | |
| CeS | |
| Molar mass | 172.18 g·mol−1 |
| Appearance | Yellow crystalline solid |
| Density | 5.9 g/cm3 |
| Melting point | 2,445 °C (4,433 °F; 2,718 K) |
| insoluble | |
| Structure | |
| cubic | |
| Related compounds | |
Other anions | Cerium monoselenide Cerium monotelluride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Cerium monosulfide is a binary inorganic compound of cerium and sulfur with the chemical formula CeS.[1][2][3][4] This is the simplest of cerium sulfides.
Synthesis
[edit]- Reduction reaction of dicerium trisulfide and cerium hydride:[5]
- Ce2S3 + CeH2 → 3CeS + H2
- Reacting cerium metal and sulfur in a planetary ball mill:[6]
- Ce + S → CeS
Physical properties
[edit]Cerium sulfide forms golden cubic crystals, with space group Fm3m and lattice parameter a = 5.763 Å. It has a NaCl-type structure.[7]
The compound melts congruently at a temperature of 2450 °C, the highest out of any known sulfide.[6]
Chemical properties
[edit]Cerium monosulfide has a wetting effect on metals, and it is relatively stable to metals other than platinum. It can react violently with platinum to form an intermetallic compound, platinum cerium.[5]
References
[edit]- ^ Perry, Dale L. (19 April 2016). Handbook of Inorganic Compounds. CRC Press. p. 105. ISBN 978-1-4398-1462-8. Retrieved 4 April 2023.
- ^ Pauling, Linus (24 November 2014). General Chemistry. Courier Corporation. p. 635. ISBN 978-0-486-13465-9. Retrieved 4 April 2023.
- ^ Kariper, İshak Afşin (1 December 2014). "Synthesis and characterization of cerium sulfide thin film". Progress in Natural Science: Materials International. 24 (6): 663–670. Bibcode:2014PNSMI..24..663K. doi:10.1016/j.pnsc.2014.10.005. ISSN 1002-0071.
- ^ "Cerium Monosulfide". American Elements. Retrieved 4 April 2023.
- ^ a b Gibbard, Kevin B.; Allahar, Kerry N.; Kolman, David; Butt, Darryl P. (September 2008). "Kinetics of thermal synthesis of cerium sulfides". Journal of Nuclear Materials. 378 (3): 291–298. Bibcode:2008JNuM..378..291G. doi:10.1016/j.jnucmat.2008.05.013. Retrieved 4 April 2023.
- ^ a b Alanko, Gordon A.; Butt, Darryl P. (Jun 2014). "Mechanochemical Synthesis of Cerium Monosulfide". Journal of the American Ceramic Society. 97. doi:10.1111/jace.13018.
- ^ Marcon, Jean-Pierre (15 Jan 1969). Contribution to the study of actinide sulfides (Thesis). Faculte des Sciences de l'Universite de Paris (France).
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