Diphenylphosphite
From Wikipedia the free encyclopedia
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| Names | |
|---|---|
| Preferred IUPAC name Diphenyl phosphonate | |
| Other names Phosphonic acid, diphenyl ester | |
| Identifiers | |
3D model (JSmol) | |
| ChEMBL | |
| ChemSpider | |
| ECHA InfoCard | 100.022.911 |
PubChem CID | |
| UNII | |
CompTox Dashboard (EPA) | |
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| Properties | |
| C12H11O3P | |
| Molar mass | 234.191 g·mol−1 |
| Appearance | colorless liquid |
| Density | 1.2268 g/cm3 |
| Melting point | 12 °C (54 °F; 285 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Diphenylphosphite is a diorganophosphite with the formula (C6H5O)2P(O)H. The molecule is tetrahedral. It is a colorless viscous liquid. The compounds can be prepared by treating phosphorus trichloride with phenol. Many analogues can be prepared similarly. One illustrative reaction, diphenylphosphite, aldehydes, and amines react to afford aminophosphonates (Kabachnik–Fields reaction).[1]
See also[edit]
References[edit]
- ^ Bhagat, Srikant; Chakraborti, Asit K. (2007). "An Extremely Efficient Three-Component Reaction of Aldehydes/Ketones, Amines, and Phosphites Kabachnik-Fields reaction for the Synthesis of α-Aminophosphonates Catalyzed by Magnesium Perchlorate". Journal of Organic Chemistry. 72 (4): 1263–1270. doi:10.1021/jo062140i. PMID 17253748.