Decene
Names | |
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Preferred IUPAC name Dec-1-ene | |
Other names Alpha Olefin C10; Decylene; α-Decene; 1-decene | |
Identifiers | |
3D model (JSmol) | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.011.654 |
EC Number |
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PubChem CID | |
RTECS number |
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UNII | |
UN number | 3295, 1993 |
CompTox Dashboard (EPA) | |
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Properties | |
C10H20 | |
Molar mass | 140.270 g·mol−1 |
Density | 0.74 g/cm3[1] |
Melting point | −66.3 °C (−87.3 °F; 206.8 K)[1] |
Boiling point | 172 °C (342 °F; 445 K)[1] |
Hazards | |
GHS labelling: | |
Danger | |
H226, H304, H410 | |
P210, P233, P240, P241, P242, P243, P273, P280, P301+P310, P303+P361+P353, P331, P370+P378, P391, P403+P235, P405, P501 | |
Related compounds | |
Related Alkenes | Octene Nonene Undecene Dodecene |
Related compounds | Decane Decanol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Decene /dɛkiːn/ is an organic compound with the chemical formula C10H20. Decene contains a chain of ten carbon atoms with one double bond, making it an alkene. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance. As an alpha olefin, it is used as a comonomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids and alkylated aromatics.[2]
The industrial processes used in the production of dec-1-ene are oligomerization of ethylene by the Ziegler process or by the cracking of petrochemical waxes.[3]
In ethenolysis, methyl oleate, the methyl ester of oleic acid, converts to 1-decene and methyl 9-decenoate:[4]
Dec-1-ene has been isolated from the leaves and rhizome of the plant Farfugium japonicum and has been detected as the initial product in the microbial degradation of n-decane.
References
[edit]- ^ a b c Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
- ^ http://www.ineosoligomers.com/media/files/lao/LAO%20C10%20Data%20Sheet.pdf 1-Decene (Alpha Olefin C10)], ineosoligomers.com
- ^ Alfa Olefins Archived 2017-05-17 at the Wayback Machine, SIDS Initial Assessment Report
- ^ Marinescu, Smaranda C.; Schrock, Richard R.; Müller, Peter; Hoveyda, Amir H. (2009). "Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum". J. Am. Chem. Soc. 131 (31): 10840–10841. doi:10.1021/ja904786y. PMID 19618951.
External links
[edit]- Entry C872059 in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD)